FOREST+


Systems for photocatalytic conversion using sunlight for valorizing CO2 and other pollutants is one of the current topics that is attracting the most scientific attention. That is because of the enormous significance of being able to provide clean energy sources by recycling CO2 and mitigating problems related with pollution. Significant progress has been made in recent years related with developing photoactive materials, like nanoparticles on semiconductor oxides, perovskites, graphene and CQDs (Carbon Quantum Dot), etc. But, it is also necessary to make progress with highly efficient devices that allow suitable contact between the reagents, photocatalyser and light. To those ends, the PC003-004 FOREST+ collaborative project, which was granted and financed in the 2019 call-for-proposals, consists of fabricating microreactors made using direct 3D printing to carry out photocatalytic reactions.

Nanostructured materials based on titanium modified with dopants (Cu) and metal nanoparticles (Au and Ag) have been incorporated into the microreactors as photocatalysing materials. Likewise, those materials are partially modified to carry out their conversion in MOF (metal organic frameworks), which are materials with a high absorption capacity that will have a positive effect on photovoltaic reactions of converting CO2 into useful products, which is the primary goal of the project. Those new materials that have an increased absorption capacity and good photocatalytic properties encourage us to continue along this line of development for increasing CO2 conversion capacity.

 

The main goals that have been achieved are the following.

A photoreaction system based on an integrating sphere to control the lighting of the experiments done in the microreactors better was fabricated.

Microreactors were designed and fabricated using direct 3D printing and photoactive materials were integrated into them.

Highly photoactive TiO2 nanoparticles, doped with metals like Cu and stable liquid dispersions of them were fabricated using the flame pyrolysis technique.

A partial synthesis of MOF using the photocatalyser dopants to increase the CO2 absorption capacity was done.

A study of the optical properties of the photocatalysers for their potential use as photonic crystals was done.


  • Año: 2019
  • Sector estratégico: Industria de la energía verde
  • Líder del proyecto: UNIVERSIDAD PÚBLICA DE NAVARRA
  • Socios del proyecto: LUREDERRA. FUNDACIÓN PARA EL DESARROLLO ECONÓMICO Y SOCIAL
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